A triazole-templated ring-closing metathesis for constructing novel fused and bridged triazoles.

نویسندگان

  • Xuejun Zhang
  • Richard P Hsung
  • Hongyan Li
چکیده

The feasibility of trapping the vinyl copper intermediate generated in situ from azide-[3 + 2] cycloadditions and viability of employing these triazoles as unique templates for ring-closing metathesis are described here; this work effectively combines the two powerful reactions for the first time to construct various de novo fused and bridged triazoles that are otherwise not trivial to synthesize.

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عنوان ژورنال:
  • Chemical communications

دوره 23  شماره 

صفحات  -

تاریخ انتشار 2007